[1]郑金云,冯祥明..芳香分子在氧化偶联聚合中的连接方式研究[J].郑州大学学报(工学版),2008,29(02):116-119.[doi:10.3969/j.issn.1671-6833.2008.02.030]
 Zheng Jinyun,Feng Xiangming.Study on the linkage mode of aromatic molecules in oxidative coupling polymerization[J].Journal of Zhengzhou University (Engineering Science),2008,29(02):116-119.[doi:10.3969/j.issn.1671-6833.2008.02.030]
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芳香分子在氧化偶联聚合中的连接方式研究()
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《郑州大学学报(工学版)》[ISSN:1671-6833/CN:41-1339/T]

卷:
29
期数:
2008年02期
页码:
116-119
栏目:
出版日期:
1900-01-01

文章信息/Info

Title:
Study on the linkage mode of aromatic molecules in oxidative coupling polymerization
作者:
郑金云冯祥明.
郑州大学,化学系,河南,郑州,450001, 郑州大学,化学系,河南,郑州,450001
Author(s):
Zheng Jinyun; Feng Xiangming
关键词:
1H NMR 氧化偶联聚合 芳香分子 连接方式
Keywords:
DOI:
10.3969/j.issn.1671-6833.2008.02.030
文献标志码:
A
摘要:
利用氧化偶联聚合反应制备了5种含均四甲苯和对二己氧基苯、蒽、芴、N-乙基咔唑以及反式对苯乙烯的共聚物.对这几种共聚物的1H NMR谱做了测试,利用均四甲苯的特殊结构,对其它几种单体的1H NMR信号做了归属,重点讨论这几种芳香分子在氧化偶联聚合反应中的连接方式.结论与氧化偶联聚合机理基本相符.
Abstract:
Five copolymers containing homotetraluene, p-dihexyloxybenzene, anthracene, fluorene, N-ethylcarbazole and trans-pstyrene were prepared by oxidative coupling polymerization. The 5H NMR spectra of these copolymers were tested, and the 1H NMR signals of other monomers were attributed by using the special structure of homotetraluene, focusing on the connection mode of these aromatic molecules in oxidative coupling polymerization. The conclusion is basically consistent with the oxidative coupling polymerization mechanism.

更新日期/Last Update: 1900-01-01