[1]钟科,王雪,张勐,等.单组份聚氨酯固化规律及黏结特性研究[J].郑州大学学报(工学版),2021,42(06):81-86.[doi:10.13705/j.issn.1671-6833.2021.04.027]
　Zhong Ke,Wang Xue,Zhang Meng,et al.Curing and Adhesive Characteristics of Single-Component Polyurethane Binders[J].Journal of Zhengzhou University (Engineering Science),2021,42(06):81-86.[doi:10.13705/j.issn.1671-6833.2021.04.027]
点击复制

单组份聚氨酯固化规律及黏结特性研究
()
分享到：

《郑州大学学报(工学版)》[ISSN:1671-6833/CN:41-1339/T]

卷:
42
期数:
2021年06期
页码:
81-86
栏目:
出版日期:
2021-11-10

文章信息/Info

Title:
Curing and Adhesive Characteristics of Single-Component Polyurethane Binders
作者:
钟科; 王雪; 张勐; 孙明志; 孙晟凯; 龚演
重庆交通大学土木工程学院;交通运输部公路科学研究院;道路结构与材料交通运输行业重点实验室;
Author(s):
Zhong Ke; Wang Xue; Zhang Meng; Sun Mingzhi; Sun Shengkai; Gong Yan;
School of Civil Engineering, Chongqing Jiaotong University; Highway Science Research Institute of the Ministry of Transport; Key Laboratory of Road Structure and Materials Transportation Industry;
关键词:
Keywords:
monocomponent polyurethane;  curing;  adhesion characteristics;  isocyanate index;  urea index
DOI:
10.13705/j.issn.1671-6833.2021.04.027
文献标志码:
A
摘要:
单组份聚氨酯是一种粘结性能优异的有机高分子化合物，可作为路面混合料的胶粘剂。本文分别通过傅里叶红外光谱、拉拔、剪切试验研究了两种单组份的固化规律和粘结特性。结果表明，在自然固化条件下，PU-I和PU-II的异氰酸酯指数逐渐下降，而脲基指数则逐渐增长；固化4d后，聚氨酯的异氰酸酯含量和脲基含量变化较小，且4~7天PU-I和PU-II的异氰酸酯指数和脲基指数的变异系数分别为10%、2%，PU-II的异氰酸酯指数和脲基指数的变异系数分别为2%、2%，属于小变异，表明该材料已基本达到完全固化状态。聚氨酯粘结体系的拉拔强度和剪切强度随着固化时间的增长，呈增大的趋势，且石料-聚氨酯-石料粘结体系界面间的拉拔、剪切强度均优于石料-聚氨酯-橡胶、橡胶-聚氨酯-橡胶粘结体系，橡胶-聚氨酯-橡胶粘结体系界面的拉拔强度最差，石料-聚氨酯-橡胶粘结体系的剪切强度最差。
Abstract:
Monocomponent polyurethane is a reactive adhesive, and its mechanical properties are better than those of conventional asphalt binders, but the reaction process is easily affected by environmental factors such as temperature, air and water, etc. During the paving and rolling construction of polyurethane mixes, it is necessary to strictly control the construction time nodes of each process in combination with the site temperature and humidity working conditions.In order to popularize the application of single-component polyurethane in road, curing and adhesive characteristics of monocomponent polyurethane were studied in this paper. Curing and adhesion characteristics of two single-component polyurethane (PU) binders were studied from FTIR, pull-out and shear tests. With the increase of natural curing conditions, the results showed that the isocyanate index of PU-I and PU-II decreased, while the urea index had the opposite trend. Both the isocyanate index and urea index of PU were stable after 4 days natural curing,and the variation coefficients of isocyanate index and urea index of PU-I and PU-II were 10% and 2%, 2% and 2%, respectively in 4-7 days, which belong to small variations, indicating that PU had basically reached the fully cured state. With the increase of curing time, the pull-out strength and shear strength of polyurethane bonding system generally increased, and the pull-out and shear strength of stone-polyurethane-stone interface were better than those stone-polyurethane-rubber, rubber-polyurethane-rubber bonding system. The pull-out strength of rubber-polyurethane-rubber interface was the worst, and the shear strength of stone-polyurethane-rubber interface was the worst.

参考文献/References:

[1] CONG L,YANG F,GUO G H,et al.The use of polyurethane for asphalt pavement engineering applications:a state-of-the-art review[J].Construction and building materials,2019,225:1012-1025.

[2] 孙铭鑫.聚氨酯空隙弹性路面混合料的性能研究[D].南京:东南大学,2016.
[3] CHEN J,YIN X J,WANG H,et al.Evaluation of durability and functional performance of porous polyurethane mixture in porous pavement[J].Journal of cleaner production,2018,188:12-19.
[4] OLEJNIK A,GOSZ K,PISZCZYK L.Kinetics of cross-linking processes of fast-curing polyurethane system[J].Thermochimica acta,2020,683:178435.
[5] REEGEN S L,FRISCH K C.Catalytic effect of urethane groups on reaction of alcohols and isocyanates[J].Journal of polymer science part A-1:polymer chemistry,1966,4(9):2321-2322.
[6] SMITH H A.Effect of urethane groups on the reaction of alcohols with isocyanates[J].Journal of polymer science part A-1:polymer chemistry,1968,6(5):1299-1306.
[7] HE Y,ZHANG X Y,ZHANG X F,et al.A recycling model of excess toluene diisocyanate isomers in the preparation of polyurethane prepolymer[J].Journal of applied polymer science,2013,127(3):2176-2183.
[8] 季节,索智,文博,等.水、温拌剂对沥青-集料界面粘附能力的影响[J].中国公路学报,2015,28(7):25-30.
[9] BASSE ASPLUND J O,BOWDEN T,MATHISEN T,et al.Variable hard segment length in poly(urethane urea) through excess of diisocyanate and vapor phase addition of water[J].Macromolecules,2006,39(13):4380-4385.
[10] 胡孝勇,陈薇,郭祀远.HDI缩二脲聚氨酯固化剂合成与残余HDI的分离[J].涂料工业,2008,38(10):45-46,49.
[11] BAZMARA B,TAHERSIMA M,BEHRAVAN A.Influence of thermoplastic polyurethane and synthesized polyurethane additive in performance of asphalt pavements[J].Construction and building materials,2018,166:1-11.
[12] 赵永利,顾凡,黄晓明.基于FTIR的SBS改性沥青老化特性分析[J].建筑材料学报,2011,14(5):620-623.
[13] 张国宝,赵根锁.醚/酯共聚型聚氨酯弹性体的化学组成研究[J].郑州工业大学学报,1997,18(4):70-75.
[14] 张磊.煤沥青基中间相沥青的制备与性能研究[D].郑州:郑州大学,2018.
[15] 季节,马榕达,郑文华,等.TLA和DCLR对沥青与集料黏附性的影响[J].重庆交通大学学报(自然科学版),2018,37(1):54-61.
[16] 袁峻,董文姣,钱武彬,等.基于超声波的沥青-集料粘附性试验方法研究[J].科学技术与工程,2013,13(5):1388-1391,1396.
[17] 豆莹莹,魏定邦,李晓民,等.沥青-集料界面黏附性衰减机理研究[J].建筑材料学报,2019,22(5):771-779.
[18] 侯航舰.沥青粘结层抗剪强度试验探析[J].郑州大学学报(工学版),2006,27(3):38-41,58.

更新日期/Last Update: 2021-12-17