[1]刘敏,刘大壮,韦建国,等.氯化聚丙烯与甲苯烷基化反应的研究[J].郑州大学学报(工学版),2006,27(01):121-124.[doi:10.3969/j.issn.1671-6833.2006.01.030]
　LIU Min,LIU Dazhuang,Wei Jianguo,et al.Study of the alkylation reaction of chlorinated polypropylene with toluene[J].Journal of Zhengzhou University (Engineering Science),2006,27(01):121-124.[doi:10.3969/j.issn.1671-6833.2006.01.030]

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氯化聚丙烯与甲苯烷基化反应的研究()

分享到：

《郑州大学学报(工学版)》[ISSN:1671-6833/CN:41-1339/T]

卷:

27

期数:

2006年01期

页码:

121-124

栏目:

出版日期:

1900-01-01

文章信息/Info

Title:

Study of the alkylation reaction of chlorinated polypropylene with toluene

作者:

刘敏; 刘大壮; 韦建国; 等.

郑州大学化工学院,河南,郑州,450002, 郑州大学化工学院,河南,郑州,450002, 郑州大学化工学院,河南,郑州,450002, 郑州大学化工学院,河南,郑州,450002, 郑州大学化工学院,河南,郑州,450002

Author(s):

LIU Min; LIU Dazhuang; Wei Jianguo; etc

关键词:

氯化聚丙烯;  烷基化反应;  烷化剂;  动力学;  稀释比值

Keywords:

Chlorinated polypropylene;  Alkylation reactions;  alkylating agent;  Dynamics;  Dilution ratio

DOI:

10.3969/j.issn.1671-6833.2006.01.030

文献标志码:

A

摘要:

研究了氯化聚丙烯与甲苯在三氯化铝(AlCl3)催化下的烷基化反应.红外谱图表明,在原来的CPP分子链上接上了芳环基团.测定了一系列的动力学数据,通过数据拟合确定了动力学参数,得到反应动力学模型,并检验了动力学方程的可靠性.改性后的氯化聚丙烯与200#汽油的相容性得到改善.

Abstract:

The alkylation reaction between chlorinated polypropylene and toluene catalyzed by aluminum chloride (AlCl3) was studied. The infrared spectra showed that an aromatic ring group was attached to the original CPP molecular chain. A series of kinetic data were determined, the kinetic parameters were determined by data fitting, the reaction kinetic model was obtained, and the reliability of the kinetic equation was verified. The compatibility of the modified chlorinated polypropylene with 200# gasoline was improved.

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